language cognition theory recommended that the social environment, learner emotions and motivation play a key role in language achievements and outcomes. This study mainly examined the relationship between environment, emotions (anxiety), motivation and learning outcomes. SEMs were utilized in factors analysis as a flexible class of models for multivariate correlated factors including student anxiety, circumstance changing anxiety and language learning motivation to assess the effectiveness and interaction of language learning achievements in tutorial-CALL teaching method. 300 students in one China university were randomly chosen as research participants. Confirmatory factor analyses and internal consistency reliabilities were satisfactory in all questionnaires. Anxiety and social circumstance changing were confirmed by statistical results. The structural equation method for learner anxiety and learner motivation had an acceptable fit. According to analysis results, it was found that the environmental circumstance and learning motivation have a positive correlation with language achievements. Furthermore, another finding was that improvements in learner emotion has a positive effect on sustainable and effective language outcomes. The results support previous work and emphasize that moderate anxiety and positive learning motivation should be taken into account clearly to evaluate language outcomes.