摘要详情
30 / 2023-08-01 21:04:21
Synthesis, structure and reactivity of metal-phosphaketenes
Phosphaketenes,group 13,group 14
摘要录用
Synthesis, structure and reactivity of metal-phosphaketenes
P. Dhawan, Essen/D, S. Schulz*, Esssen/D.
Prof. Dr. Stephan Schulz, Universität Duisburg Essen, Universitätsstr. 2, 45141 Essen.
Since the 1980s, there has been significant interest in organometallic chemistry regarding the synthesis and investigation of compounds containing multiple bonding interactions between main group elements.[1] Metallaphosphenes are of particular interest in this field, and they are constructed using phosphaketenes as appropriate precursors. These phosphaketenes are prepared through salt metathesis reactions involving Na(OCP)(dioxane)2.5 and halogen-substituted metal complexes. When reacted with monovalent main group metal complexes, the relatively weak P-CO bond leads to the release of carbon monoxide, resulting in the formation of a M=P double bond.
P. Dhawan, Essen/D, S. Schulz*, Esssen/D.
Prof. Dr. Stephan Schulz, Universität Duisburg Essen, Universitätsstr. 2, 45141 Essen.
Since the 1980s, there has been significant interest in organometallic chemistry regarding the synthesis and investigation of compounds containing multiple bonding interactions between main group elements.[1] Metallaphosphenes are of particular interest in this field, and they are constructed using phosphaketenes as appropriate precursors. These phosphaketenes are prepared through salt metathesis reactions involving Na(OCP)(dioxane)2.5 and halogen-substituted metal complexes. When reacted with monovalent main group metal complexes, the relatively weak P-CO bond leads to the release of carbon monoxide, resulting in the formation of a M=P double bond.
重要日期
-
会议日期
11月12日
2023
至11月16日
2023
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10月24日 2023
初稿截稿日期
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11月16日 2023
注册截止日期
主办单位
Ningbo University
